摘要
MS2 -4 (M =Mo、W、V等 )阴离子由于灵活多样的配位方式可形成特殊的构造单元而被广泛应用于分子设计中。本文对含有MS2 -4 及 1,10 phenanthroline的混配金属配合物Zn(phen) 2 WS4 和Zn(phen) 2 MoS4的晶体进行红外光谱和拉曼光谱的研究并讨论了谱学与结构的关系。
The negative ion,MS 2- 4(M=Mo,W,V ect.),is used widely in molecule designed as construction fragment because of its various ligand mode.The IR and Raman spectra of the crystals Zn(phen) 2WS 4 and Zn(phen) 2MoS 4 with mixed ligands MS 2- 4 and 1,10 phenanthroline have been investigated,and the coincidence between the spectrum and the structure has been discussed as well.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
2000年第6期847-848,共2页
Spectroscopy and Spectral Analysis
基金
国家自然科学基金资助