摘要
综述了桥联杯[6]芳烃的合成及构象固定等方面的研究进展,并以下缘1,4位桥联杯[6]芳烃,杯[6]冠醚和杯[6]穴醚及其类似物等主体分子为重点,综述了桥联杯[6]芳烃在分子识别和超分子化学领域中应用研究的最新进展。
Bridged calix[6]arenas, which have the advandge of preorganizing the calixarene conformations suitable for molecular recognition, are becoming one of the latest central interests in calixarene chemistry. This paper reviews the research progress of bridged calix [ 6 ] arenes, including their preparations, conformation immobilization and spectral characteristics, molecular recognition ability, applications in the field of synthetic organic chemistry and supramolecular chemistry. Several types of important members in this family, such as rigid - spacer- briged calix[6]arenes, calix[6] crowns, and calix[6] cryptands are highlighted in detail.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2000年第6期841-849,共9页
Chinese Journal of Organic Chemistry
关键词
杯芳烃化学
芳烃
合成
构象固定
calixarene chemistry, bridged calix [ 6 ] arenes, synthesis, conformation immobilization, molecular recognition
