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Hydrometallurgical application for treating a Nigerian chalcopyrite ore in chloride medium:Part I.Dissolution kinetics assessment 被引量:1

Hydrometallurgical application for treating a Nigerian chalcopyrite ore in chloride medium:Part I.Dissolution kinetics assessment
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摘要 The dissolution kinetics of a Nigerian chalcopyrite ore in hydrochloric acid was studied in this article. Acid concentration, reaction temperature, and ore particle size were chosen as experimental parameters. The chemical and morphological studies of the ore before and after leaching at optimal conditions were carried out by X-ray diffraction (XRD) and scanning electron microscopy (SEM). It is revealed that increasing the acid concentration and system temperature and decreasing the ore particle size greatly enhances the dissolution rate. The dissolution kinetics was found to follow the shrinking core model for the diffusion control mechanism where the activation energy (Ea) of 32.92 kJ.mo1-1 was obtained for the process and supported by morphological changes at a higher dissolution of 91.33%. The dissolution kinetics of a Nigerian chalcopyrite ore in hydrochloric acid was studied in this article. Acid concentration, reaction temperature, and ore particle size were chosen as experimental parameters. The chemical and morphological studies of the ore before and after leaching at optimal conditions were carried out by X-ray diffraction (XRD) and scanning electron microscopy (SEM). It is revealed that increasing the acid concentration and system temperature and decreasing the ore particle size greatly enhances the dissolution rate. The dissolution kinetics was found to follow the shrinking core model for the diffusion control mechanism where the activation energy (Ea) of 32.92 kJ.mo1-1 was obtained for the process and supported by morphological changes at a higher dissolution of 91.33%.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2013年第11期1021-1028,共8页 矿物冶金与材料学报(英文版)
关键词 CHALCOPYRITE HYDROMETALLURGY leaching hydrochloric acid DISSOLUTION ore treatment chalcopyrite hydrometallurgy leaching, hydrochloric acid dissolution ore treatment
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