摘要
利用氨功能化的MCM-41催化了丙二腈与α,β-不饱和酮的Michael加成反应,甲醇作溶剂,常温下反应产率高达99%,同时得到了一系列高产率的氰基类衍生物,催化剂具有合成简单、环境友好、多次循环利用等特点.
Michael addition reaction of α, β-unsaturated ketones and malononitrile that catalyzed by amine functionalized MCM-41 in methanol afforded a series of cyano derivatives with high yield (up to 99%). The products were afforded at room temperature. Moreover, the catalyst was also found to easiness to handle up, friendly environment, and excellent recyclability.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2013年第11期2391-2395,共5页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.21162026
20962018
20862015)资助项目~~