混合烷烃γ辐射磺氯酰化制备烷基石油磺酸钠——Ⅱ.偶氮二异丁腈对烷烃γ辐射磺氯酰化反应的敏化作用研究

GAMMA RADIATION SULFOCHLORINATION OF MIXTURE OF PARAFFINS AND NAPHTHENES (MPN)Ⅱ.THE STUDY ON AZOBISISOBUTYLNITRILE(AIBN) SENSITIZATION OF RADIATION SULFOCHLORINATION

为了对以多种结构类型的混合烷烃为原料的γ辐射磺氯酰化法合成烷基石油横酸钠的反应提高产率,所以对偶氮二异丁腈(AIBN)敏化效应进行了研究,并对其敏化机理进行了探讨。以AIBN作敏化剂进行磺氯酰化反应,可使烷基磺酰氯具有较大的产率。

To increase RSO_2Cl yield of γ-radiation sulfochlorination of MPN,this paper studied the sensitization effect of AIBN on the radiation sulfochlorinationof MPN and discussed the sensitization mechanisms. The RSO_2Cl yields were greatlyincreased tor radiation sulfochlorination of MPN by AIBN sensitization.