期刊文献+

CuO/Ce_(1-x)Zr_xO_2催化分解NO的研究 被引量:1

Research of the Decomposition of NO over CuO/Ce_(1-x)Zr_xO_2
下载PDF
导出
摘要 NO对环境的影响日益严重,如果不有效将其消除掉,将会对环境及人的健康产生极大的危害。因此,目前各国都在研究廉价消除NO污染的方法。采用共沉淀法制备了催化剂CuO/Ce1-x Zr x O2,利用XRD对其晶相进行表征,H2-TPR研究了其氧化还原能力,以NO的转化效率作为评价指标。结果表明:适当比例Zr的加入以及适当比例的CuO能提高活性。 NO increased serious for the environment. If not be eliminated effectively, it would be serious risks on the environment and human health. Therefore, the low- cost ways to eliminate pollution NO were studied in many countries currently. CuO/Ce1-xZrxO2 catalyst was prepared by the method of co - precipitation. XRD was used to characterize the crystalline phase structure of the prepared catalyst. The redox ability of the catalyst was studied by H2 - TPR. Using the conversion efficiency of NO as an evaluation index can make an evaluation of catalytic activity. The test results showed that adding the proper proportion of Zr and CuO can improve the catalytic activity.
机构地区 黑河学院理化系
出处 《广州化工》 CAS 2013年第22期43-44,共2页 GuangZhou Chemical Industry
基金 黑龙江省教育厅科学技术项目(项目代码:12511347)
关键词 氧化铜 NO 催化剂 copper oxide nitric oxide catalyst
  • 相关文献

参考文献4

  • 1Yokoi Y, Uchida H. Catalytic activity of perovskite - type oxide catalysts for direct decomposition of No: Correlation between cluster model calculations and temperature - programmed desorption experiments [ J ]. Catal Today, 1998,42 ( 1 - 2 ) : 167 - 174.
  • 2许树军,朱宇君,袁福龙,李丽,陈利强.复合氧化物La_(1-x)Ba_xCoO_3对NO直接分解的研究[J].黑龙江大学自然科学学报,2008,25(5):667-670. 被引量:5
  • 3陈利强,CHEN Gabriel,朱宇君,袁福龙.La_(2-x)Ba_xCuO_4和La_(1-x)Ba_xFeO_3催化分解NO研究(英文)[J].黑龙江大学自然科学学报,2009,26(3):385-389. 被引量:3
  • 4Mathew S M, Umbarkar S B, Dongare M K. NO storage behavior of BaO in different structural environment in NSR catalysts [ J 1 Catalysis Conununications, 2007, 8 (8) : 1178 - 1182.

二级参考文献9

  • 1Tofan C, Klvana D, Kirchnerova J. Direct decompsirion of nitric oxide over perovskite - type catalysts Part 1 Activity when no oxygen is added to the feed [ J ]. Applied Catalysis A : General,2002,223 : 275 - 286.
  • 2Teraoka Y,Harada T, Fukuda H,et al. Catalytic property of perovskite -type oxides for the direct decomposition of nitrieoxide [J]. Chem Lett, 1990,(1 ) :1 -4.
  • 3Ishihara T, Ando M, Sada K, et al. Direct decomposition of NO into N2 and O2 over La(Ba) Mn (In)O3 perovskite oxide[J]. Journal of Catalysis, 2003,220: 104 - 114.
  • 4Broqvist P, Gronbeck H, Fridell E, et al. NOx storage on BaO : theory and experiment [ J ]. Catalysis Today,2004,96 : 71 - 78.
  • 5Tofield B C, Scott W R. Oxidative nonstoichiometry in perovskite, an experimental survey, the defect structure of an oxidized Lanthanum Manganite by powder neutron diffraction[ J ]. Juornal of Solid State Chemistry, 1974,10:183 -194.
  • 6Huang L, Bassir M, Kaliaguine S. Reducibility of Co^3 + in perovskite -type LaCoO3 and promotion of copper on the reduction of Co^3 + in perovskite - type oxides[ J]. Applied Surface Science, 2005,243 : 360 - 375.
  • 7Teraoka Y, Harada T, Kagawa S. Reaction mechanism of direct decomposition of nitric oxide over Co - and Mn - based perovskite - type oxides [ J ]. J Chem Soc Faraday Trans, 1998,94 ( 3 ) : 1887 - 1891.
  • 8吴越,高利珍,于作龙.La_(2-x)Sr_xCuO_(4-λ)复合氧化物的合成、表征和氨的氧化催化性能的研究[J].化学学报,1997,55(1):56-63. 被引量:11
  • 9俞守耕.钙钛矿型氧化物在净化汽车尾气催化剂中的应用[J].贵金属,2001,22(2):61-66. 被引量:19

共引文献4

同被引文献8

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部