小分子修饰高分子负载镍配合物催化性能研究

The studies on cataytic properties of monomolecular modified polymer-bound nickel complexes

对负载性镍配合物的催化进行了研究，结果表明这些催化剂对催化环己烯氧化，催化活性和选择性均较高．

PBPY-Ni-L complexes possess high selectivity and activity for the catalytic oxidation of cyclohexene. The main oxidation products of cyclohexene are 2-cyclohexen-1-ol and2-cyclohexen-l-one. The influence of experimental parameters on the reaction was also investigated.