烯烃的反马氏氢胺化反应

Catalytic anti-Markovnikov Hydroamination of Alkenes

胺类及其衍生物是一类重要的有机化合物。通过烯烃氢胺化反应直接合成胺类及其衍生物是众多合成胺类化合物方法中最高效和原子经济性最高的方法。烯烃的反马氏氢胺化反应是合成高价值直链型胺类化合物的最优方法。最近有关此类反应的报道,主要集中在开发新的催化体系研究上。本文以此为主线,综述了烯烃反马氏氢胺化反应的最新进展。

Amines and their derivatives are of fundamental importance organic compounds. The hydroamination of olefins is the most effective and atom economic procedures to synthesis amines, and the anti - markovnikov products are usually more important industrial applications. Scientists recently have focused on the various in-vestigation of catalytic systems. The development and recent progress of anti - markovnikov hydroamination of alkenes is reviewed in this paper.