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环氧基封端的聚氨酯改性明胶的研究 被引量:4

The research of epoxy-terminated polyurethane-modified gelatin
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摘要 研究了带有环氧基的聚氨酯对明胶进行改性的实验条件,探讨了不同配比环氧基封端的水性聚氨酯改性明胶膜的机械性能、接触角、透湿性能的影响.结果表明:当聚氨酯和明胶的质量比为5∶5时,改性膜的机械性能最佳,即断裂伸长率可达317.18%,抗张强度为40.28N·mm2,接触角为65.3°,透湿量可达309g·m-2.24h-1.使用红外光谱对环氧基封端的聚氨酯、明胶、聚氨酯改性明胶进行了结构表征. Studied the modified gela oxy group, discussed the effect of sile strength that different ratios o tin experimental conditions by a polyurethane with an ep the mechanical properties, the contact angles and the ten f the epoxy-terminated gelatin film. The results show that at the mass ratio of 5 modified film is the best; the elongation rate is 317.18% waterborne polyurethane modified : 5, the mechanical property of the ; the tensile strength is 40.28 N · mm2 ; the contact angle is 65.3 °;the water vapor permeability is 309 g · m 2 · 24 h 1. U sing infrared spectroscopy to characterize epoxy-terminated polyurethane, gelatin, polyure thane-modified gelatin.
出处 《陕西科技大学学报(自然科学版)》 2013年第6期77-81,共5页 Journal of Shaanxi University of Science & Technology
基金 陕西省科技厅自然科学基金项目(2007B13) 陕西科技大学研究生创新基金项目
关键词 聚氨酯 环氧基 明胶 polyurethane epoxy group gelatin
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  • 1Sheridan M H,Shea L D,Peters M C,et al. Biodegradable polymer scaffolds for tissue engineering capable of sus tained growth factor delivery[J]. Controll Rel, 2000,65= 91 102.
  • 2王远亮.改性明胶与皮革填充性能研究[J].明胶科学与技术,1994,14(2):67-72. 被引量:10
  • 3庄思永 刘杏芹.改性明胶用盐絮凝对乳剂感光度的影响[J].明胶科学与技术,1986,6(1):19-22.
  • 4李正军,陈玲,罗永娥.蛋白质类涂饰成膜材料的进展[J].皮革科学与工程,2002,12(4):21-25. 被引量:2
  • 5刘倩,贺丽蓉,潘姝言,张倩,林炜.丙烯酸树脂涂饰剂的合成及明胶对其改性的研究[J].中国皮革,2008,37(23):19-23. 被引量:4
  • 6陈友强.过硫酸铵-尿素引发丙烯酸甲酯与明胶接枝共聚[J].应用化学,2000,17(4):453-455. 被引量:9
  • 7Kuwajima T, Yoshida H, Hayashi K. Grafting polymeriza- tion of vinyl monomers with gelation[J]. Appl. Polym. Sci, 1976,20 967.
  • 8Petite H, Duval J L, Frei V. Cyto compatibility of calfperi- cardium treated by glutaradehyde and by the acylazide methods in anorganotypic culture model[J]. Biomateriais,1995,16(13)1 003-1 018.
  • 9Sophie Duquesne, Michel Ire Bras, Serge Bourbigot, et al Expandable graphite : A fire retardant additive for polyure thane coatings[J]. Fire and Materials, 2003,27 ( 3 ) : 103 117.
  • 10Yang X F, Vang C, Tallman D E, et al. Weathering deg- radation of a polyurethane coating[J]. Polymer Degrada- tion and Stability,2001,74(2) :341 351.

二级参考文献47

共引文献51

同被引文献53

  • 1舒铂,赵亚平,于文利.以明胶和蔗糖为复合壁材的番茄红素微胶囊化研究[J].食品工业科技,2004,25(9):52-54. 被引量:19
  • 2刘小玲,林莹,尹秀华,黄华清.罗非鱼皮胶原肽的制备及抗氧化活性研究[J].食品与机械,2007,23(3):92-95. 被引量:32
  • 3安广杰,王璋.改性水解明胶的理化性质分析——热力学和流变学性质[J].食品科学,2007,28(7):68-72. 被引量:3
  • 4Liu Hai-ying,Li Ding.Extraction and properties of gelatin from channel catfish (Ietalurus punetaus) skin[J].Food Science and Technology,2008,41(3):414-419.
  • 5Phanngam Kaewruang,Soottawat BenjakuU Thummanoon Prodpran,et al.Impact of divalent salts and bovine gelatin on gel properties of phosphorylated gelatin from the skin of unicorn leatherjacket[J].Food Science and Technology,2014,55(2):477-482.
  • 6Li Cheng Sou,Yang Hong-shun.Effects of salt and sugar addi- tion on the physicochemical properties and nanostructure of fish gelatin[J],Food Hydrocolloids,2015(45):72-82.
  • 7Sarabia A I,GoA mez-GuilleAn M C,Montero P.The effect of added salts on the viscoelastic properties of fish skin gelatin[J].Food Chemistry,2000,70(1):71-76.
  • 8Saravanan M,Panduranga Rao K.Pectin-gelatin and alginate- gelatin complex coacervation for controlled drug delivery:Influ- ence of anionic polysaccharides and drugs being encapsulated on physicochemical properties of microcapsules[J].Carbohydrate Polymers,2010,80(3),808-816.
  • 9He Sheng-bin,Yin Ting,Zhen Jin-wang,et al.Cross-linking of gelatin by chlorine dioxide steam[J].Food Hydrocolloids,2015(45):63-71.
  • 10Jalal Rouhi,Shahrom Mahmud,Nima Naderi,et al.Physical properties of fish gelatin-based bio-nanocomposite films incor- porated with ZnO nanorods[J].Nanoscale Research Letters,2013,8(1);364-370.

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