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Solid State Physics View of Liquid State Chemistry—Electrical conduction in pure water

Solid State Physics View of Liquid State Chemistry—Electrical conduction in pure water
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摘要 Engineering characterization of water has produced huge varieties of materials with special properties to meet human needs. Equilibrium properties of water-based liquids are well understood via localized atomic and molecular orbital theories. However, the mechanism of electrical conductivity of pure water has proven elusive. We show here it is trapping limited drift of positive and negative quasi-protons （or protons and proton-vacancies） on the extended water lattice, which is accounted for by the long-range correlation inherent in the Fermion （electrons and protons） and Boson （phonons） energy band theory of quasi-particles in solids, with vigorous adherence to equilibrium and nonequilibrium states. Engineering characterization of water has produced huge varieties of materials with special properties to meet human needs. Equilibrium properties of water-based liquids are well understood via localized atomic and molecular orbital theories. However, the mechanism of electrical conductivity of pure water has proven elusive. We show here it is trapping limited drift of positive and negative quasi-protons （or protons and proton-vacancies） on the extended water lattice, which is accounted for by the long-range correlation inherent in the Fermion （electrons and protons） and Boson （phonons） energy band theory of quasi-particles in solids, with vigorous adherence to equilibrium and nonequilibrium states.
作者 揭斌斌 薩支唐
机构地区 Department of Physics Chinese Academy of Sciences
出处 《Journal of Semiconductors》 EI CAS CSCD 2013年第12期1-8,共8页 半导体学报（英文版）
关键词 solid state physics liquid state chemistry pure water PROTON proton vacancy band and bond solid state physics liquid state chemistry pure water proton proton vacancy band and bond
分类号 O48 [理学—固体物理]
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参考文献36

  • 1J. D. Bernal and R. H. Fowler, "A theory of water and ionic so- lution, with particular reference to hydrogen and hydroxyl ions", J. Chem. Phys. 1(8), 515-548, August, 1933. Received April 29, 1933. (University of Cambridge, England.).
  • 2Linus Pauling, "The structure and entropy of ice and other crystals with some randomness of atomic arrangement", J. Amer. Chem. Soc. 57(12), 2680-2684, December 1935. Re- ceived September 24, 1935. (Gates Chemical Laboratory, Cal- tech, Pasadena.).
  • 3W. F. Giauque and H. L. Hohnston, "Symmetrical and Antisym- metrical Hydrogen and the Third Law of Thermodynamics. Ther- mal Equilibrium and the Triple Point Pressure", J. Amer. Chem. Soc. 50, 3221-3228, 192.
  • 4J. O. Clayton and W. F. Giauque, "The Heat Capacity and Entropy of Carbon Monoxide. Heat of Vaporation. Vapor Pressures of Solid and Liquid. Free Energy to 5000~K. From Spectroscopic Data", J. Amer. Chem. Soc. 54, 2610-2626, 1932.
  • 5W. W. Blue and W. F. Giauque, "The Heat Capacity and Vapor Pressure of Solid and Liquid Nitrous Oxide. The Entropy from its Band Spectrum", J. Amer. Chem. Soc. 57,991-997, 1935.
  • 6Quoted by Pauling in Ref. [2]. (UC Berkeley) J. Frenkel, Kinetic Theory of Liquids, Oxford University Press, 1946 from 1943 manuscript. Dover Republication, 1955. 488pp.
  • 7J. M. Ziman, Models of Disorder--The theoretical physics of homogenously disordered system, Cambridge University Press, 1979. 525pp.
  • 8Sah Chihtang and Jie Binbin, "Semiconductor Physics View of Liquid State Chemistry", Invited Paper at the Special Session, the Sah Pen-Tung 111th Anniversary Symposium, of the 2013 Na- tional Fall-Meeting of the Chinese Physical Society, September 13-15, 2013, Xiamen University, Xiamen, Fujian, China.
  • 9Gilbert Newton Lewis and Merle Randall, Thermodynamics and the Free Energy of Chemical Substances, McGraw-Hill Book Company, New York, 1923. 653pp. (Textbook of gradu- ate course in Chemistry at UC Berkeley, learned by Linda Chang in September 1959.).
  • 10See especially Chapter II. Definitions: The Concept of Equilibrium. p.8-20. Chih-Tang Sah, Fundamentals of Solid-State Electronics, World Scientific Publishing Co., Singapore, 1991. 1010pp.
Journal of Semiconductors
2013年 第12期

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