也谈绝对熵和热力学第三定律问题

DEALING WITH FHE PROBLEM ABOUT ABSOLUTE ENTROPY AND THE THIRD LAM OF THERMODYNAMICS

本文是从统计角度入手辅以近年来科学研究成果,对较长时期应用的“绝对零度”,“完美晶体”,“绝对熵”,“热力学第三定律”等热力学概念提出否定其客观存在性的初步观点。并从实际出发对其适用提出一点粗浅看法,从而提出将“绝对零度”改为“规定零度”,“绝对熵”改为“规定熵”,最好不再应用“完美晶体”说法,把热力学第三定律视为人为提出的定律,只因它解决了一般热力学计算问题而誉称而已。

This article starts from the direction of the statisiics, assisted by theaehievements of sclence and technology in recent years. The initial view thatnegates the existence of concepts, which are the long used thermodynamicconcepts-- 'absolute zero degree', 'perfect erystalloid', 'absolutc entropy','the third law of thermodynamics', etc, has been given out. For the useful-ness, some cruble ideas are given from practise. So converting the 'absolute zerodegree', to 'prescribing zero degree' and converting the 'absolute entropy' to'prescribing entropy' have been suggested in the article. Meanwhile, it's betternot using the opinion of 'perfect crystalloid' any longer and thinking the'third law of thermodynamics' as man made law that just solved the usualcalculation problems of thermodynamics.