摘要
Ce1–x Smx O2–δ-attapulgite(ATP) nanocomposites were successfully prepared via a facile microwave approach.This was a facile and rapid process requiring only low power of microwave irradiation(160 W).The catalytic performance of the Ce1–x Smx O2–δ-ATP nanocomposites with different Sm contents for degradation of methylene blue(MB) was systematically evaluated.The Ce1–x Smx O2–δ-ATP nanocomposites showed enhanced catalytic activities compared with pure CeO2/ATP.Specifically,the catalytic activities of Ce1–x Smx O2–δ-ATP nanocomposites increased with increase in Sm content from x=0.0 to 0.3.The introduction of an optimal amount of Sm3+into CeO2 contributed to the formation of structure defects and electronic defects in the oxide lattice,which could increase concentration of oxygen vacancies.However,further increasing Sm content to x=0.4 induced the formation of more agglomerates,leading to decreased catalytic activity.It was believed that this facile,rapid microwave-assisted strategy was scalable and could be applied to synthesize other nanocomposites for different applications.
Ce1–x Smx O2–δ-attapulgite(ATP) nanocomposites were successfully prepared via a facile microwave approach.This was a facile and rapid process requiring only low power of microwave irradiation(160 W).The catalytic performance of the Ce1–x Smx O2–δ-ATP nanocomposites with different Sm contents for degradation of methylene blue(MB) was systematically evaluated.The Ce1–x Smx O2–δ-ATP nanocomposites showed enhanced catalytic activities compared with pure CeO2/ATP.Specifically,the catalytic activities of Ce1–x Smx O2–δ-ATP nanocomposites increased with increase in Sm content from x=0.0 to 0.3.The introduction of an optimal amount of Sm3+into CeO2 contributed to the formation of structure defects and electronic defects in the oxide lattice,which could increase concentration of oxygen vacancies.However,further increasing Sm content to x=0.4 induced the formation of more agglomerates,leading to decreased catalytic activity.It was believed that this facile,rapid microwave-assisted strategy was scalable and could be applied to synthesize other nanocomposites for different applications.
基金
supported by the National Natural Science Foundation of China(NSFC51002016)
Applied Basic Research Projects of Changzhou(CJ20115021)
Jiangsu Overseas Research & Training Program for University Prominent Young and Middle-aged Teachers and Presidents