丙烯酰基苯并三氮唑及其聚合物光物理过程的研究

THE STUDY ON THE PHOTOPHYSICS PROCESS IN ACRYL-OYLBENZOTRIAZOLE AND ITS POLYMER

1-N-丙烯酰基苯并三氮唑(ABT)及其聚合物-聚丙烯酰基苯并三氮唑(PABT)作为功能高分子材料的母体和重要原料已引起人们的重视。如报道[1]利用PABT可制备聚丙烯酸及其各种不同的酯类、带芳酰胺或脂肪酰胺侧基的各种聚酰胺化合物等。文献[2]报道了以1-氢苯并三氮唑(1-HBT)

This paper is concerned with the study on the photophysics process in acryloylbenzotria-zole(ABT) and polyacryloylbenzotriazole (PABT). The exciplex fluorescence spectra between ABT or PABT and sulfuric acid or trifluoroacetic acid were observed respectively. It is useful for understanding photoreaction mechanism of ABT.