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Diels-Alder反应的全新认识 被引量：1

On Diels-Alder new reactions
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摘要 综述了 1 9篇参考文献中关于 Diels- Alder反应的研究新成果 :水相 Diels- Alder反应 ;C60 的Diels- Alder反应 ;超分子作用下的 Diels- Alder反应以及反双烯合成的应用。对 Diels- Alder反应的全新认识无论是对有机合成设计还是有机化学教学内容更新都具有重要意义。 A review with 19 references on the current Diels Alder reactions,i.e. Diels Alder reactions in aqueous solution,C 60 Diels Alder reactions and antidiene compounds synthesis,which the reactions are important both design of the organic compounds synthesis and teaching organic chemistry.
作者 王大伟 郭百凯
机构地区 渭南师范学院化学系
出处 《宝鸡文理学院学报（自然科学版）》 CAS 2000年第4期271-275,共5页 Journal of Baoji University of Arts and Sciences(Natural Science Edition)
基金 陕西省教委专项基金资助项目!(9840 38)
关键词 DIELS-ALDER反应 反双烯合成 C60 超分子作用 反应机理 反应条件 review Diels Alder reaction antidiene synthesis fullerene(C 60 ) supermolecule effect
分类号 O621.259.4 [理学—有机化学] O623.122 [理学—有机化学]
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参考文献10

  • 1HAYASHI Y,ROHDE JJ,COREY E J.A novel chiral super-Lewis acid catalyst for enantioselective synthesis[].Journal of the American Chemical Society.1996
  • 2BLOKZIJIW,ENGBERTSJB F N.Hydrophobiceffects:opinion and fact[].Angewandte Chemie.1993
  • 3COREY E J,LOH T P.Firstapplication of attractive intramolecular interactions to the design of chiral catalystsfor highly enantioselective Diels-Alder reactions[].Journal of the American Chemical Society.1991
  • 4RIDEOUT D C,BRESLOW R.Hydrophobic acceleration of Diels-Alder reactions[].Journal of the American Chemical Society.1980
  • 5HADDON R C.Chemistry of the fullerenes:the maniffestation of strain in a class of continuous aromaticmolecules[].Science.1993
  • 6BLOKZIJI W,BLANDAMER M J,ENGBERTS J B F N.Diels-Alder reactions in aqueous solutions,enforcedhydrophobic interactions between diene and dienophile[].Journal of the American Chemical Society.1991
  • 7LUBINEAU A,AUGE J,LUBIN N.Hetero Diels-Alder reaction in water,synthesis ofα-hydroxy-γ-lactones[].Tetrahedron Letters.1991
  • 8LARSEN S D,GRIECO P A.Aza Diles-Alder reactions in aqueous solution:cyclocondensation of dienes withsimple iminium saltgenerated Mannich conditions[].Journal of the American Chemical Society.1985
  • 9KHAM S I,OLIVER A M,PADDON-ROW M N,etal.Synthesis of a rigid"ball-and-chain"donor-acceptorsystem through Diels-Alder functionalization of buckminsterfullerene (C6 0 )[].Journal of the American Chemical Society.1993
  • 10RUBIN Y,KHAN S,FREEDBERG D I.Synthesis and X-ray structure of a Diels-Alder adduct of fullerene C6 0[].Journal of the American Chemical Society.1993

同被引文献14

  • 1周建峰.水相Diels-Alder反应[J].大学化学,1996,11(3):28-33. 被引量：4
  • 2LI C, CHAN T-H. Organic Reactions in Aqueous Media [ M]. New York: Wiley, 1997.
  • 3GRIECO P A. Organic Synthesis in Water [ M ]. London:Blacky Academic and Professional, 1998.
  • 4BRESLOW R, RIDEOUT D. Hydrophobic acceleration of Diels-Alder reactions [J]. J. Am. Chem. Soc. , 1980,102:7816 - 7819.
  • 5GRIECO P A, GAMER P, HE Z-M."Micellar"catalysis in aqueous intermolecular Diels-Alder reaction; rate acceleation and enhanced selectivity [ J ]. Tetrahedron Lett. , 1983,24:1 897-1 899.
  • 6KOBAGASHI S, HACHIYA I, ARAKI M, et al. Scandium trifluoromethanesulfonate ( Sc( OTf)3 ). A novel reusable catalyst in the Diels-Alder reaction [ J ]. Tetrahedron Lett.,1993,34(23) :3 755 - 3 758.
  • 7LUBINEAU A, AUGE J, LUBIN N. Aqueous cycloaddition using glycoorganic subskates: Facial stereoselectivity in Diels-Alder reactions of a chiral diene derived from D-glyceraldehyde [ J ]. J. Chem. Soc., Perkin Trans. 1, 1990,(11):3 011 - 3 015.
  • 8LUBINEAU A,AUGE J. LUBIN N, Hetero Diels-Alder reaction in water, synthesis of α-hydroxy-γ-lactones[ J]. Tetrahedron Lett. , 1991,32:7 529- 7 530.
  • 9LUBINEAU A, QUENEAU Y. Aqueous cycload-ditions using glyco-organic substrates, 1. stereo-chemical course of the reaction [J]. J. Org. Chem. ,1987,52:1 001- 1 007.
  • 10NARUSE M,AOYAGI S,KIBAYASHI C.New chiral route to ( - )-Swainsonine via an aqueous acylnitroso cycloaddition approach[J]. J. Org. Chem. , 1994,59:1 358- 1 364.

引证文献1

宝鸡文理学院学报（自然科学版）
2000年 第4期

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