期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution 被引量：1

Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution
下载PDF
导出
摘要 It is important to know how ILs(ionic liquids)influence organic reaction.In this paper,activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically.Through the study on typical organic reactions happened in ILs,such as Diels-Alder,esterification and Friedel-Crafts reaction,the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions. It is important to know how ILs（ionic liquids） influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.
作者 马征 董晓霞 胡玉峰 张柏松 徐长英 刘艳升
机构地区 Shandong Province Key laboratory of Plant Nutrition and Fertilizer State Key Laboratory of Heavy Oil Processing
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第12期1370-1375,共6页 中国化学工程学报（英文版）
基金 Supported by the National Natural Science Foundation of China（21176248）
关键词 ionic liquid activity coefficients at infinite dilution organic reactions 离子液体 有机反应 无限稀释 活度系数 Friedel-Crafts反应 有机化合物 选择性反应 酯化反应
分类号 O646.1 [理学—物理化学] O621.25 [理学—有机化学]
  • 相关文献

参考文献33

  • 1Welton, T. "Room-temperature ionic liquids. Solvents for synthesis and catalysis", Chem. Rev. 99, 2071-2084 (1999).
  • 2Sherif, F.G, Shyu, LJ. Greco, C.C. "Linear alxylbenzene formation using low temperature ionic liquid", US Pat. 5824832 (1998).
  • 3Matsumoto, K,, Hagiwara, R. Ito, Y. "Structural analysis of 1-ethyl-3-methyl-imidazolium bifluoride melt", Nucl. lnstrum. Methods Phys. Res. Sect. B. 199, 29-33 (2003).
  • 4Fischer, T. Sethi, A. Welton, T. "Diels-Alder reaction in room-temperature ionic liquids", Tetrahedron Len. 40, 793-796 (1999).
  • 5Lei, Z.G, Chen, B.H. Li, C.Y. Liu, H. "Predictive molecular ther- modynamic models for liquid solvents, solid salts, polymers, and ionic liquids", Chem. Rev. 108, 1419-1455 (2008).
  • 6Martins, M.A.P. Frizzo, C.P. Moreira, D.N. Zanatta, N. Bonacorso, H.G, "Ionic liquids in heterocyclic synthesis", Chem. Rev. 108, 2015-2050 (2008).
  • 7Tanam, K. Burk, E, "QSPR analysis for infinite dilution activity co- efficients of organic compounds", J. Mol. Model. 12, 417-421 (2006).
  • 8Ge, M.L. Xiong, J.M. Wang, L.S. "Prediction of activity coeffi- cients at infinite dilution of organic compouds in ionic liquid", Chi- nese Science Bulletin, 54 (10), 1419-1423 (2009).
  • 9Padovani, A.M. Suleiman, D. "Simple prediction of limiting activ- ity coefficients of nonelectrolytes in water at 25 °C", AIChE J. 43 (12), 3271-3273 (1997).
  • 10Lee, S.H. Lee, S.B. "The Hildebrand solubility parameters, cohe- sive energy densities and internal energies of 1-alkyl-3-methyl- imidazolium-based room temperature ionic liquids", Chem. Com- mun. 21, 3469-3471 (2005).

同被引文献11

引证文献1

二级引证文献2

Chinese Journal of Chemical Engineering
2013年 第12期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部