插烯噁唑类化合物的研究(Ⅰ)——反-1,2-双[2′-(5′-苯基噁唑基)]乙烯及其衍生物的合成与光性能的研究

Research on Vinylene Inserted Oxazoles——The Syntheses and Opticall Properties of Trans-1,2-bis[2'-(5'-Substituted Phenyl Oxazolyl)]ethylene

本文合成了12种反-1,2-双[2’-(5’-苯基嚼唑基)]乙烯(简称POEOP)及其衍生物。讨论了化合物的结构同其红外光谱、紫外光谱、荧光光谱、荧光量子产率及激光转换效率间的关系,并与POOP类化合物的光性能进行了比较。

Trans-1, 2-bis[2'-(5'-phenyl oxazolyl)]ethylene(POEOP) and eleven of its substituted phenyl derivatives were synthesized. The relationships between the constitution of those compounds and their IR, UV, FL spectra, fluorescence quantum yields, laser conversion efficiencies were discussed.