氢电极反应绝对电极电位的表达式

An Expression of Absolute Electrode Potential of Hydrogen Electrode Reaction

本文将量子电化学热活化理论的氢电极反应的电子传递条件式在紧密双电层中展开,得到该电极反应的绝对电极电位表达式。

The object of this paper is to give an expression of the absolute electrode potential of hydrogen electrode reaction which is obtained from the electron transition condition expression of the hydrogen electrode reaction of the thermal activation theory extended in the compact double layer and the expression is expressed as where c is the activation energy of the chemical reaction and μis the chemical potential of the electron in metal, q is the electrode charge density and K=I+L-R+A, which can be obtained from the equation