摘要
本文报道求取i_f~E曲线的一种双电解池差分装置。通过扣除交流示波极谱法总电流中双电层充电电流i_c,测量法拉第电流对工作电极电位的曲线(即i_t~E曲线),可提高灵敏度。
To improve the sensitivity of cyclic derivative chronopotentiometry, the instrument is constructed by using two electrolytic cells, the measuring cell and the blank cell, to cancel most of the charging current of the electrical double layer. it-E curve is obtained and used in analysis in place of dE/dt-E curve.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1991年第7期879-881,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
交流示波极谱
if^E曲线
极谱
Cyclic derivative chronopotentiometry, i1-E curve, Differiential instrument, Twin elec-trolytic cells