甲酸甲酯与烯烃反应合成酯的催化体系及反应机理

THE CATALYTIC SYSTEM AND REACTION MECHANISM OF METHYL FORMATE REACTING WITH ALKENE FOR SYNTHESIS OF ESTERS

随着甲酸甲酯大规模工业化的实现 ,加速其下游产品的开发利用 ,日益成为普遍关注的一大课题。近年来 ,利用甲酸甲酯替代CO/CH3OH与烯烃的加氢酯化反应也逐渐成为研究热点。本文系统介绍了甲酸甲酯与烯烃反应合成酯的催化体系 ,并对反应机理进行了讨论。

With the industry realization of methyl formate on a great scale,the considerable attention has been paid to use and development of its downstream products.In recent years,special attention has also been devoted to hydroesterification of alkene using methyl formate instead of CO/CH 3OH.This paper reviews the catalytic system of methyl formate reacting with alkene for synthesis of esters,in addition,the reaction mechanism is also discussed.