摘要
用灼烧、红外光谱、质谱、热分析和分光光度法研究了漆酚与FeCl_3的反应关系、产物的组成和结构特征及其性能。由此揭示了传统黑推光漆的内在本质和特性,为黑推光漆的加工及提高性能等,提供了理论依据。此外还对漆酚与FeCl_3的反应机理进行了探讨。
Urushiol-ferrous chelate polymer was obtained by reaction of urushiol and FeCl3. IR, MS and chemical analysis showed the chelate is composed of 4 urushiol quinones and 1 ferrous atom. Urushiol-Fe chelate possesses the same high thermol stability as traditional black polish lacquer and plays important part in the blackness. The reaction mechanism of urushiol and FeCl3 has been suggested.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1991年第5期32-35,共4页
Polymer Materials Science & Engineering
基金
国家自然科学基金
关键词
黑推光漆
生漆
漆酚
高聚物
合成
urushiol-ferrous chelate polymer, thermol, stability black polish lacquer, blackness.
