复合阻燃剂阻燃硬质聚氨酯泡沫塑料的性能研究

Research on Properties of Rigid Polyurethane Foam Plastics Modifi ed by Composite Flame Retardant

制备了复合阻燃剂阻燃硬质聚氨酯(PUR-R)泡沫塑料,研究了复合阻燃剂甲基膦酸二甲酯(DMMP)、三(2-氯异丙基)磷酸酯(TCPP)、可膨胀型石墨(EG)和氢氧化铝(ATH)对PUR-R泡沫塑料阻燃性能的影响,采用正交试验确定了复合阻燃剂的最佳配比。用极限氧指数(LOI)测定仪、烟密度测定仪和万能试验机测定了阻燃PUR-R泡沫塑料的LOI、烟密度等级和压缩强度,结果表明,当DMMP,TCPP,EG,ATH的质量比为2∶2∶3∶3时,在25份聚醚多元醇中添加12份复合阻燃剂,制备的阻燃PUR-R泡沫塑料的LOI达26.3%,烟密度等级为77.63,压缩强度为0.18 MPa,阻燃PUR-R泡沫塑料具有良好的综合性能。

Rigid polyurethane（PUR.R） foam plastics modified by composite flame retardant were prepared. Effects of composite flame retardant dimethyl methylphosphonate（DMMP）, trichloropropylphosphate（TCPP）, expandable graphite（EG） and aluminum hydroxide（ATH） on the properties of PUR-R foam plastics modified by composite flame retardant were studied. The optimum proportion of the composite flame retardant was determined with orthogonal experiment. The limited oxygen index（LOI）, the smoke density rating and the compressive strength were obtained by LOI instrument, smoke density determinator and material testing machine. The results show that when the mass ratio ofDMMP, TCPP, EG, ATH are 2 ： 2 ： 3 ： 3,12 phr composite flame retardant is added to 25 phr polyether polyols, the LOI, the smoke density rating and the compressive strength of PUR-R foam plastics modified by composite flame retardant are 26.3%, 77.63 and 0.18 MPa respectively, PUR-R foam plastics modified by composite flame retardant have better comprehensive properties.