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聚酯废料乙二醇解聚反应的研究 被引量:1

Study on Depolymerization of Poly(ethylene terephthatate) Waste Materials by Ethylene Glycol
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摘要 在选定的条件下,使聚酯废料乙二醇解聚,反应产物中BHET含量高,易精制,对乙二醇醚化反应也有所抑制。BHET缩聚后得到的聚酯的各顷指标达到了纺丝要求,可纺性能良好。 Poly(ethylene terephatate) (PET) waste materials were depolymerized by ethylene glycol under the selecting reaction conditions. Bis (2-hydroxyethyl) terephthatate(BHET)content of the resultant was considerable. The resultant was easily purified. The etherification reaction of ethylene glycol was also restrained. BHET was polymerized to give poly (ethylene terephatate), the quality index of which was up to standard. The spinnability of PET was better.
出处 《高分子通报》 CAS CSCD 1991年第3期176-179,共4页 Polymer Bulletin
关键词 聚酯废料 乙二醇 解聚反应 Poly(ethylene terephatate)waste, Ethylene glycol, Depolymerizing reaction
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  • 2邰玉蕾,赵亚娟,马希晨,宋辉.废旧聚酯瓶片的回收新技术[J].塑料科技,2004,32(4):61-64. 被引量:21
  • 3杨治伟,赵国梁,张大省.PET在EG中的醇解反应[J].北京服装学院学报(自然科学版),1994,14(1):29-33. 被引量:9
  • 4EVERHART W D, MAKAR K M, RUDOPH R G. Recovery of Polyester From Contaminated PolyesterWaate: US, 982284 [ P ]. 1999 - 9-20.
  • 5Guoxi Xi, Maixi Lu, Chen Sun. Study on depolymerization of waste polyethylene terephthalate into monomer of bis (2 - hydroxyethyl terephthalate) [J]. Polymer Degradation and Stability. 2005, 87 (1) :117-120.
  • 6Cheng - Ho Chen. Study of glycolysis of poly ( ethylene terephthalate) recycled from post consumer soft drink bottles [ J ]. Appl Polym sci. 2003 (87) :2004-2010.
  • 7Ghaemy M, Mossadde K, Depolymerisation of poly ( ethylene terephthalate) fibre wastes using ethylene glycol [ J ]. Polymer Degradation and Stability., 2005 (90) :570-576.
  • 8Shukla S R, Harad Ajay M, Jawale Laxmikant S. Recycling of waste PET into useful textflo auxiliaries[J]. Waste Manage ,2006 (130) :113-118.
  • 9Medlhat S F. Mechanical characteristics of modified unsaturated polyester derived from poly (ethylene terephthalate ) [ J ]. Soc Chem,2002(51 ) : 183-189.
  • 10李永贵,李准准,佴友兵,葛明桥.聚酯纤维乙二醇醇解法(Ⅰ):醇解工艺[J].纺织学报,2007,28(11):21-24. 被引量:29

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