新型三脚架结构配体及其配合物的合成与结构表征

The Synthesis and Structural Characteristics of a new Tripodal Ligand and its Complexes

以三乙醇胺、水杨醛、对氯苯胺为初始原料,合成了一个新型的三脚架结构席夫碱配体,并与Ni、Cu过渡金属氯化物反应制备了两种过渡金属的配合物,经元素分析、红外光谱、紫外光谱、核磁共振谱进行了结构表征,确定了配体及配合物的组成.

A kind of new tripodal Schiff base ligand was prepared by using triethanolamine, salicylaldehyde and p-chloroaniline as materials. Then we prepared the complexes of the ligand with transition metal chlorides. The ligand and its complexes were characterized by elemental analyses,IR, UV, HNMR. The composition of the ligand and complexes are confirmed.