C207铜基催化剂常压甲醇分解反应动力学(Ⅰ)本征动力学模型

Reaction Kinetics of Methanol Decomposition over C207 Cu-Based Catalyst (Ⅰ) Model of Intrinsic Kinetics

在直流流动积分反应器中常压下研究了C207催化剂甲醇分解反应本征动力学。实验温度、气体组成与甲醇合成工业条件相接近。以实验測定数据应用改进高斯-牛顿法对动力学模型参数进行估值,获得甲醇分解反应本征动力学方程。

The intrinsic kinetics of the methanol decomposition at atmospheric pressure over C207 catalyst are studied in a tubular-flow integral reactor. The ranges of the temperature and the gas composition were similar with the conditions of synthesis of industrial methanol. By parameter estimation for kinetic model using the improved Gauss-Newton method, the intrinsic reeation rate equation has been obtained.