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Steric Effects in the Cl+CHD3(v1=1) Reaction

Steric Effects in the Cl+CHD3(v1=1) Reaction
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摘要 A recent study has revealed a full 3-dimentional reactive scattering picture of the reaction CI+CHD3(v1=1) as the C1 atoms attack CHD3 from various directions respective to the C-H stretching bond. The reported polarization-dependent differential cross sections provide the most detailed characterization of the influences of reagent alignments on reactivity. To convey the stereo-specific information more accessible to general chemists, we show here, by proper symmetry considerations, how to retrieve from the measurements the relative integral and differential cross sections of two most common collision geometries: the end-on versus side-on attacks. The results, albeit coarse-grained, provide an appealing picture that not only reinforces our intuition about chemical reactivity, but also sheds more light on the conventional (unpolarized) attributes.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第6期705-709,I0004,共6页 化学物理学报(英文)
关键词 Steric effect Integrate cross section Cylindrical symmetry Slice image Crossed beam technique 反应散射 立体效果 CL 微分截面 化学反应性 反应路线 偏振相关 几何形状
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