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二丁氨基锌酞菁的合成与性质

Synthesis and properties of dibutyl aminoethyl zinc phthalocyanine
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摘要 以4-硝基邻苯二甲腈、二正丁胺、亚氨基二丙酸为原料,合成2(3)-(N,N-二丙酸氨基)-9(10),16(17),23(24)-(N,N-二丁氨基)锌酞菁(FPC)。通过IR谱、UV-Vis谱、元素分析和1H NMR谱表征其结构,比较了产物在TiO2薄膜和N,N-二甲基甲酰胺(DMF)溶液中的UV-Vis谱。结果证明,所合成的化合物FPC在DMF中具有良好的溶解性,且在一定浓度范围内不发生集聚现象。FPC的UV-Vis谱发生明显红移,能级与纳米TiO2薄膜匹配,适用于制备太阳能电池。 4-nitro phthalonitrile, di-n-butylamine, amino propionic acid synthesize 2 （3）-（N, N-dibutyl amino acid）-9 （10）, 16 （17） ,23（24）-（N,N-dibutyl amino） in PC （FPC）. By IR spectrum, UV-Vis spectra, elemental analysis, 1H NMR spectroscopy, this research characterizes the structure and compares the UV-Vis spectra in TiO2 film and the solution of N,N-dimethyl- formamide （DMF）. The results prove that the compound FPC has a good solubility in DMF. and the agglomeration phenomenon does not occur within a certain concentration range. There is obvious red shift of UV-Vis spectra in FPC. And the energy level matches the nano-sizcd TiO2 film, which is suitable for the manufacture of solar cells.
作者 张学俊 朱白青 韩明亮
机构地区 中北大学理学院
出处 《山西化工》 2013年第6期1-3,24,共4页 Shanxi Chemical Industry
基金 山西省自然科学基金项目(2011011022-4)
关键词 氨基锌酞菁 集聚 合成 表征 amino zinc phrhalocyanine agglomeration synthesis characterization
分类号 TQ613.5 [化学工程—精细化工]
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参考文献12

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山西化工
2013年 第6期

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