N,N-四氯邻苯二甲酰基-13-硝基-7,7-C_(60)-脱异丙基脱氢枞胺的合成

Synthesis of N,N-tetrachlorophthaloyl-13-nitro- 7,7-C_(60)-deisopropyldehydroabietylamine

以脱氢枞胺为起始原料,经酰化、苄基氧化、硝化、缩合和卡宾加成反应合成了一个新化合物——N,N-四氯邻苯二甲酰基-13-硝基-7,7-C60-脱异丙基脱氢枞胺,总收率7.4%,其结构经UV-Vis,1H NMR,13C NMR,IR,MS和元素分析表征。

A novel compound,N,N-tetrachlorophthaloyl-13-nitro-7,7-C 60-deisopropyldehydroabietylamine,was successfully synthesized from dehydroabietylamine by acylation,benzylic oxidation,nitrification,condensation and addition reaction of carbene. The structure was characterized by UV-Vis, 1H NMR,13C NMR,IR,MS and elemental analysis.