穿插和缠绕结构配位聚合物的合成与性能研究

The study of syntheses and properties of interpenetrated and entangled coordination polymers

配位聚合物由于具有独特的结构和优异的性能,近年来受到国内外的持续广泛关注,已成为当前化学、物理、材料、医学以及生命科学等领域的热点研究之一,并日益呈现出迅猛发展的良好势头.有关此类化合物的显著特征是:在合成时,其结构中经常发生不同程度的穿插和缠绕现象,使得合成目标化合物的性能产生根本上的改变.因此,本文主要结合本课题组近期的研究工作,评述了穿插和缠绕结构配位聚合物及其相关化合物的合成、结构与气体吸附分离性能应用等方面的研究进展.

The study of coordination polymers （CPs） has already become a focused research topic in the filed of chemistry, physics, materials science and biology and received ever-increasing attention of the chemists in the world due to its intrinsic structures and properties. The notable feature of CPs is that interpenetration and entanglement often occur in the synthesized process, which has an essential influence on the properties of the targeted complexes. Therefore, this review mainly introduced the progress of the syntheses, structures, gas adsorption and separation of the interpenetrated and entangled CPs combining with the research works of our group.