摘要
利用HgC12与1-(苯并三氮唑-1-甲基)-1-(2-丙基咪唑)(bpmi)在甲醇中反应,合成了一种双核配合物[Hg(bpmi) Cl2]2.采用X射线衍射、元素分析及红外光谱对配合物进行了结构表征.并且测定了配合物[Hg(bpmi) C12]2和配体bpmi在甲醇溶液中的荧光性质,结果表明,配合物与配体均在397 nm处有较强的荧光.
The dinuclear complex [ Hg(bpmi)C12 ] 2 is synthesized via the reaction between HgC12 and 1 - ( ( benzotriazol - 1 - yl) methyl) - 1 - H - 1,3 - ( 2 - propyl - imdazol) ( bpmi ) in a methanol solu- tion. Its structure is confirmed by IR,elemental analysis and X- ray structural diffraction. Furthermore, we determined the fluorescence property of the bpmi ligand and the complex in a methanol solution. It turns out that the ligand and the complex display the intensive florescent at 397 nm.
出处
《河南化工》
CAS
2013年第19期40-42,共3页
Henan Chemical Industry
基金
濮阳职业技术学院自然科学基金(20BPYZYZR02)
关键词
1-(苯并三氮唑-1-甲基)-1-(2-丙基咪唑)
配合物
荧光性质
1 - ( ( benzotriazol - 1 - yl) methyl) - 1 - H - 1,3 - ( 2 - propyl - imdazol )
coordinationpolymer
fluorescence property