摘要
报道了以α-萘乙酸为原料 ,经与 SOCl2 回流反应 ,得到α-萘乙酰氯 ,再在液 -液相转移催化剂 PEG-4 0 0的催化作用下 ,α-萘乙酰氯与芳胺反应 ,合成了 10种新的α-萘乙酰芳胺 ,并经 IR、1 HNMR、1 3CNMR及元素分析确定了它们的结构 .
WT5BZ]: α naphthylacetic acid ( α NAA) was used as the raw material, α naphthylacetic acid chloride was prepared by reaction of α NAA with SOCl 2 after refluxing 14～15 h.Ten new aryl α naphthylacetylamides were synthesized through the reaction of α naphthylacetic acid chloride with ArNH 2 by using PEG 400 as liquid liquid phase transfer catalysis.Their structures were characterized by IR, 1HNMR, 13 CNMR and elemental analysis. [WT5FZ]
出处
《辽宁师范大学学报（自然科学版）》
CAS
2000年第4期381-383,共3页
Journal of Liaoning Normal University:Natural Science Edition
基金
辽宁省教育厅科研基金资助项目(9802211056)
关键词
萘乙酰芳胺
合成
相转移催化
aryl α-naphthylacetylamides
synthesize
phase transfer catalysis
