Solvothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel 3D [Ca2（HCOO）2（nds）（H2O）2]n 被引量：1

Solvothermal Synthesis, Crystal Structure and Photoluminescent Property of a Novel 3D [Ca2（HCOO）2（nds）（H2O）2]n

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摘要 A novel calcium（Ⅱ） metal-organic framework [Ca2（HCOO）2（nds）（H2O）2]n（1） with mixed 1,5-naphthalenedisulfonate sodium salt（1,5-nds） and formate as organic ligands has been obtained under solvothermal conditions.It was found that theμ3-η2∶η2 bridging mode of HCOO-in compound 1 is uncommon.Moreover,the formate,which was in situ formed from N,N＇-dimethylformamide,played an important role in the formation of 3D structure.HCOO-ligands bridged Ca（Ⅱ） ions into grid-like layers that were further pillared by the 1,5-nds ligand to form a 3D Ca-based framework.Compound 1 also exhibits a strong blue luminescence at room temperature. A novel calcium（Ⅱ） metal-organic framework [Ca2（HCOO）2（nds）（H2O）2]n（1） with mixed 1,5-naphthalenedisulfonate sodium salt（1,5-nds） and formate as organic ligands has been obtained under solvothermal conditions.It was found that theμ3-η2∶η2 bridging mode of HCOO-in compound 1 is uncommon.Moreover,the formate,which was in situ formed from N,N＇-dimethylformamide,played an important role in the formation of 3D structure.HCOO-ligands bridged Ca（Ⅱ） ions into grid-like layers that were further pillared by the 1,5-nds ligand to form a 3D Ca-based framework.Compound 1 also exhibits a strong blue luminescence at room temperature.

作者 WANG Shuang ZHANG Renchun WANG Junjie SHEN Lanlan ZENG Ying ZHANG Daojun

机构地区 College of Chemistry and Chemical Engineering College of Chemistry and Chemical Engineering

出处《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2014年第1期9-12,共4页 高等学校化学研究（英文版）

基金 Supported by the National Natural Science Foundation of China（Nos.51203109, 21301009） and the Science and Technology Foundation of Henan Province, China（No. 122102210460）.

关键词 Naphthalenedisulfonate Luminescence property Metal-organic framework Naphthalenedisulfonate Luminescence property Metal-organic framework

分类号 O643.1 [理学—物理化学] TB383 [一般工业技术—材料科学与工程]

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1QU Xue-jian,WANG Shuang,ZHANG Dao-jun,JING Xue-min,ZHANG Li-rong,LI Guang-hua,HUO Qi-sheng,LIU Yun-ling.Temperature-controlled Hydrothermal Synthesis of Copper(Ⅰ or Ⅱ) Coordination Polymers via a Variety of Copper Coordination Modes[J].Chemical Research in Chinese Universities,2012,28(4):581-584. 被引量：3

二级参考文献37

1Ferey G., Mellot-Draznieks c., Serre c., Millange F., Acc. Chem. Res., 2005, 38, 217.
2Liu Y L., Kravtsov V. c., Eddaoudi M., Angew. Chem. Int. Ed., 2008, 47,8446.
3Wang C. S, Gu X. F., Sun Y G., Gao E. 1., Zhang W. Z, Chem. Res. Chinese Universities, 2009, 25(5), 614.
4Forster PM., Burbank A. R., Livage c, Ferey G., Cheetham A. K., Chem. Commun., 2004, 368.
5Zheng B., Dong H, Bai J. F., Li Y Z., Li S. H., Scheer M., J. Am. Chem. Soc., 2008, 130,7778.
6Lin X. M., Fang H. c., Zhou Z. Y, Chen L., Zhao 1. w., Zhu S Z, Cai Y P., Cryst. Eng. Comm., 2009, l l , 847.
7Li X. P, Zhang 1. Y, Pan M., Zheng SR., Liu Y, Su C. Y, Inorg. Chem., 2007, 46, 4617.
8Lu W. G., Jiang L., Feng X. L., Lu T B., Cryst. Growth Des., 2008, 8, 986.
9Wang S., Zhang L. R., Li G. H, Huo Q. S, Liu Y L., Cryst. Eng. Comm., 2008, 10,1662.
10Zheng Y Z., Tong M. L., Chen X. M, New J Chem., 2004, 28,1412.