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聚合物载体负载TiCl_4/i-Bu_3Al催化烯烃聚合 被引量:6

Polymer-Supported Catalyst for Olefin Polymerization
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摘要 探讨了聚合物负载烯烃聚合催化剂的合成及用于聚合的研究 .研究了聚合物作为载体的催化行为 ,并通过 IR,DSC,元素分析和粘度法测定分子量等手段对催化剂及聚合物进行了表征 .包括合成聚合物负载的 Ti体系催化剂和用所合成的催化剂进行乙烯聚合 ,乙烯、丙烯与丁二烯共聚合的研究 . The polymer-supported TiCl_4 catalyst was synthesized and the catalytic features in the polymerization of ethylene and copolymerization of ethylene, propylene and butadiene in the presence of cocatalyst(Et_3Al) were studied. The supported catalyst and obtained polymers were characterized by IR, DSC, elemental analysis and viscosity molecular weight measurements.
出处 《应用化学》 CAS CSCD 北大核心 2001年第2期125-127,共3页 Chinese Journal of Applied Chemistry
基金 国家自然科学基金!资助项目 (2 99742 0 9 2 992 5 10 1) 国家重点基础研究专项经费资助!(G19990 6 480 0 )
关键词 聚合物负载催化剂 烯烃 聚合 氯化钛 polymer-supported catalyst,olefin polymerization
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参考文献4

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同被引文献31

  • 1潘建兴,杨敬一,徐心茹.聚乙烯技术新进展[J].现代化工,2005,25(8):20-22. 被引量:15
  • 2周光远 金国新 等.C13H8CR1R2C5H5MCl2(M=Ti,Zr)的合成及聚合成的研究.茂金属催化剂和聚合反应工程研讨会资料[M].杭州:-,1997..
  • 3吕立新.Ziegler-Natta催化剂结构和反应机理的研究进展——多活性中心的特征和催化剂的氢调敏感性[J].石油化工,2007,36(8):853-860. 被引量:17
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  • 10lsmayil Nurulla,Takashi Morikita,Hiroki Fukumoto. Preparation and properties of poly[(2-alkylbenzimidazole)-altthiophene]s with long Alkyl Side Chains. Macromol[J]. Chem. Phys,2001,202 : 2335-2340.

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