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Pitzer混合参数对HCl-KCl-H_2O体系25℃时溶解度预测的影响 被引量:5

Effects of Pitzer Mixing Parameters on the Solubility Prediction of HCl-KCl-H_2O System at 25 ℃
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摘要 The solubility variation of the phase system HCl-KCl-H2O at 25 ℃ is reported when θHK(interactions between two species with the same charge) and ΨHKCl(interactions among three species) are changed within ±10%. The calculated results indicate that the interactions among the three species are much stronger than that between the two species, whereas the combination of the two kinds of interactions result in great changes of the solubility of the system. This results is important for the salting out technology of the water-salt system. The solubility variation of the phase system HCl-KCl-H_2O at 25 ℃ is reported when θ_HK(interactions between two species with the same charge) and Ψ_HKCl(interactions among three species) are changed within ±10%. The calculated results indicate that the interactions among the three species are much stronger than that between the two species, whereas the combination of the two kinds of interactions result in great changes of the solubility of the system. This results is important for the salting out technology of the water-salt system.
出处 《应用化学》 CAS CSCD 北大核心 2001年第2期155-157,共3页 Chinese Journal of Applied Chemistry
基金 中国科学院重点课题!(970 393) 西北大学博士基金资助课题
关键词 溶解度预测 Pitzer混合参数 氯化钾 氯化氢 水盐体系 HCl-KCl-H_2O system,solubility prediction,Pitzer mixing parameter
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