期刊文献+

生物质源合成气催化转化制乙醇研究进展 被引量:3

Progress in Catalytic Conversion of Biomass-derived Syngas to Ethanol
下载PDF
导出
摘要 生物质气化制合成气,然后再由合成气催化转化制乙醇,已引起国内外广泛的重视,因为这是改善空气质量,增加能量资源的一条新途径。介绍了合成气制乙醇反应的特点,已研究的该反应主要催化剂类型,以及它们在CO加氢反应中的表现。并分析了现有各类催化体系和反应工艺存在的主要问题,为进一步研究开发新的催化剂和反应过程提供信息。 Gasification of biomass followed by catalytic conversion of syngas to ethanol is receiving in- creased attention all over the world, because it is considered as a new route to improve air quality and to in- crease energy resource. The reaction properties of syngas to ethanol, the main types of catalysts used and their performances in CO hydrogenation were described. The problems of the present catalytic systems and reaction conditions were discussed to provide information for further research on designing new catalyst and developing new reaction process.
作者 陶泳 高滋
出处 《化学世界》 CAS CSCD 北大核心 2014年第2期124-128,共5页 Chemical World
关键词 生物质 合成气 乙醇 催化剂 biomass syngas ethanol catalyst
  • 相关文献

参考文献18

  • 1GUPTA M,SMITH M L, SPIVEY J J. Heteroge-neous Catalytic Conversion of Dry Syngas to Ethanoland Higher Alcohols on Cu-based Catalysts [J]. ACSCatal,2011,1: 641.
  • 2TAKEUCHI K,MATSUZAKI H, ARAKAWA H,et al. Synthesis of Ethanol from Syngas over Co-Re-Sr/Si()2 Catalysts [J]. Appl Catal, 1985, 18: 325.
  • 3van der LEE G,SCHULLER B, POST H, etal. Onthe Selectivity of Rh Catalysts in the Formation ofOxygenates [J], J Catal,1986,98: 522.
  • 4DU Y H,CHEN D A,TSAI K R. Promoter Actionof Rare Earth Oxides in Rhodium/Silica Catalysts forthe Conversion of Syngas to Ethanol [J]. Appl Catal,1987,35: 77.
  • 5STEVENS R R. Process for Producing Alcoholsfrom Synthesis Gas: USP, 4882360 [P]. 11)89.
  • 6BERETTA A,SUN Q,HERMAN R G,etal. Pro-duction of Methanol and lsobutyl Alcohol Mixtures o-ver Double-bed Cesium-promoted Cu/ZnO/Cr.Oa andZn()/Cr2(). Catalysts [J]. Ind Eng Chem Res, 19%,35: 1534.
  • 7KINKADE N E. Tantalum-containing Catalyst Use-ful for Producing Alcohols from Synthesis Gas: USP,4994498 [P]. 1991.
  • 8BHASIN M M, BARTLEY W J,ELLEGEN PC, etal. Synthesis Gas Conversion over Supported Rhodi-um and Rhodium-iron Catalysts [J]. J Catal,1978,54: 120.
  • 9LID,YANGC, LI W, etal. Ni/ADM: A High Ac-tivity and Selectivity to + OH Catalyst for CatalyticConversion of Synthesis Gas to C|-Cs Mixed Alcohols[J]. Top Catal,2005,32: 233.
  • 10IRANMAHBOOB J, HILL D (X Alcohol Synthesisfrom Syngas over K2 C(h /CoS/MoS2 on ActivatedCarbon [J]. Catal Lett, 2002.78 : 49.

同被引文献44

  • 1项阳阳,周劲松,吴何来.超临界流体在生物质转化技术中的应用[J].化工进展,2012,31(S1):30-35. 被引量:5
  • 2Ke Wu YANG,Xuan Zhen JIANG,Wei Chao ZHANGD Department of Chemistry, Zhejiang University, HangZhou 310027.One-step Synthesis of n-Butanol from Ethanol Condensation over Alumina-supported Metal Catalysts[J].Chinese Chemical Letters,2004,15(12):1497-1500. 被引量:4
  • 3杨春,孟中岳.碱金属沸石上乙醇双分子缩合反应及其机理[J].Chinese Journal of Catalysis,1994,15(1):28-33. 被引量:3
  • 4Fang Li, Hongfang Ma, Haitao Zhang, et al. syngas on Mn- and Fe-promoted Rh/",/-A1203[J]. Comptes Rendus Chimie, 2014, 17(11) : 1109-1115.
  • 5YongJun Liu, Zhi-Jun Zuo, Chao Li, Xuan Deng, Wei Huang. Effect of preparation method on CuZnA1 cata.lysts for ethanol synthesis from syngas[J]. Applied Surface Science, 2015, 356, 124-127.
  • 6Yanyong Liu, Kazuhisa Murata, Megumu Inaba, sao Takahara. Synthesis of ethanol from methanol and syngas through an indirect route containing methanol dehydrogenation, DME carbonylation, and methyl acetate hydrogenolysis[J]. Fuel Processing Technology, 2013, 110: 206-213.
  • 7Yang-Jie Xu, Guo-Xiu Li, Zuo-Yu Sun. Development of biodiesel industry in China: Upon the terms of production and consumption[J]. Renewable and Sustainable Energy Reviews, 2016, 54: 318-330.
  • 8Ok Kyung Lee, Dong Ho Seong, et.al. Sustainable production of liquid biofuels from renewable microalgae biomass[J]. Journal of Industrial and Engineering Chemistry, 2015, 29: 24-31.
  • 9William I. Suh, Sanjiv K. Mishra. Etal. Direct transesterification of wet microalgal biomass for preparation of biodiesel[J]. Algal Research, 2015, 12: 405-411.
  • 10Harvind K Reddy, Tapaswy Muppaneni. et.al. Direct conversion of wet algae to crude biodiesel under supercritical ethanol conditions[J]. Fuel, 2014, 115: 720-726.

引证文献3

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部