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环氧类增容剂反应增容PLA/PBAT共混体系的研究 被引量:9

Study on PLA/PBAT Blends Prepared by Reaction Compatibilization with Epoxy Compatibilizers
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摘要 以环氧类增容剂(REC)为增容剂,采用双螺杆挤出机熔融共混制备聚乳酸(PLA)/聚对苯二甲酸己二酸丁二醇酯(PBAT)共混物。研究了增容剂对共混体系微观结构、力学性能和热性能的影响。结果表明,添加适量REC可以提高PLA与PBAT的相容性,改善PLA/PBAT共混体系的综合力学性能;REC用量为1.4份时共混体系呈现出良好的相容性,此时共混物冲击强度由26.8kJ/m2增加到62.1kJ/m2、断裂伸长率提高由222%增加到357%。 An epoxy resin was introduced into PLA/PBAT blends as a compatibilizer by melt blending using a twin screw extruder. The effect of the compatihilizer on thermal performance, mechanical properties, and microstructure of PLA/PBAT blends were investigated. It showed that the interface bonding force in the blends was enhanced by the compatibilizer, and the comprehensive mechanical properties of the blend were increased greatly. An inclusion of 1.4 phr compatibilizer increased the impact strength and elongation at break from 26.8 kJ/m^2 to62. 1 kJ/m^2 and 222% to 357 %, respectively.
出处 《中国塑料》 CAS CSCD 北大核心 2014年第2期91-95,共5页 China Plastics
基金 国家自然科学基金资助项目(51173005) 国家质量监督检验检疫总局质检公益性行业科研专项(201310256) 科技部十二五支撑计划课题(2012BAB18B04-4)
关键词 聚乳酸 聚对苯二甲酸己二酸丁二醇酯 增容剂 相容性 poly(lactic acid) poly(butyleneadipate-co-terephthalate) compatibilizer compatibility
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  • 1方少明,周立明,高丽君,张留成,赵清香,惠娟,侯振坤.PLA嵌段的聚氨酯丙烯酸酯大单体的合成及聚合物的制备[J].高分子材料科学与工程,2005,21(2):85-88. 被引量:5
  • 2宋谋道,余艺华,张邦华,郝广杰,周庆业,张莹,刘升,肖湘.乳酸、羟基乙酸均聚物及共聚物的合成与结构表征[J].离子交换与吸附,1995,11(3):245-252. 被引量:29
  • 3Ohkoshi I, Abe H, Doi Y. Polymer, 2000, 41 (15): 5985
  • 4Wang L, Ma W, Gross R A, et al. Polym Degrad Stab, 1998, 59 (1): 161
  • 5Martin O, Averous L. Polymer, 2001, 42 (14): 6209
  • 6Baiardo M, Frisoni G, Seandola M, et al. J Appl Polym Sci, 2003, 90 (7): 1731
  • 7Hiltunen K, Seppala J V, Harkonen M. Lactic acid based poly( ester-urethanes) : Use of hydroxyl terminated prepolymers in urethane synthesis [J]. Journal of Applied Polymer Science, 1997,63 ( 8 ) : 1 091 - 1 100.
  • 8Kylma j, Harkonen M, Seppala J V. Modification of lactic acid based poly ( ester-urethane ) by copolymerization [ J ]. Journal of Applied Polymer Science, 1997,63 ( 13 ) : 1 865 - 1 872.
  • 9Cohn D, Salomon A H. Designing biodegradable multiblock PCL/ PLA thermoplastic elastomers [ J ]. Biomaterials, 2005,26 ( 15 ) : 2 297 - 2 305.
  • 10Zhong Wei, Ge Jinjiel Gu Zhenyu,et al. Study on biodegradable polymer materials based on poly ( lactic acid) : I. Chain extending of low molecular weight poly( lactic acid) with methylenediphenyl diisocyanate[ J ].Journal of Applied Polymer Science, 1999,74 (10) :2546 -2551.

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