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p-Sulfonatocalix[4]arene-induced amphiphilic aggregation of fluorocarbon surfactant

p-Sulfonatocalix[4]arene-induced amphiphilic aggregation of fluorocarbon surfactant
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摘要 Sulfonatocalix[4]arene lowers the critical aggregation concentration of fluorocarbon surfactant pronouncedly by a factor of ca.100 to form binary amphiphilic aggregates on the basis of host-guest complexation,which was identified by1H NMR spectroscopy,fluorescence spectroscopy,optical transmittance spectroscopy,dynamic laser scattering,high-resolution transmission electron microscopy,scanning electron microscopy,and surface tension experiments.Moreover,the resulting aggregates can respond to external stimuli,including temperature and inclusion of competitor guest.Therefore,the present system may have potential applications in drug delivery systems. Sulfonatocalix[4]arene lowers the critical aggregation concentration of fluorocarbon surfactant pronouncedly by a factor of ca.100 to form binary amphiphilic aggregates on the basis of host-guest complexation,which was identified by1H NMR spectroscopy,fluorescence spectroscopy,optical transmittance spectroscopy,dynamic laser scattering,high-resolution transmission electron microscopy,scanning electron microscopy,and surface tension experiments.Moreover,the resulting aggregates can respond to external stimuli,including temperature and inclusion of competitor guest.Therefore,the present system may have potential applications in drug delivery systems.
作者 CAO Yu WANG YiXuan GUO DongSheng LIU Yu
机构地区 State Key Laboratory of Elemento-Organic Chemistry Department of Chemistry
出处 《Science China Chemistry》 SCIE EI CAS 2014年第3期371-378,共8页 中国科学（化学英文版）
基金 supported by the National Basic Research Program of China(2011CB932502) the National Natural Science Foundation of China(91227107 and 21172119)
关键词 氟碳表面活性剂 芳烃 磺化 动态激光光散射 透射电子显微镜 扫描电子显微镜 荧光光谱法 聚合 calixarene-induced aggregates,fluorocarbon surfactant,supra-amphiphile,multi-stimuli responses
分类号 O647.2 [理学—物理化学]
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2014年 第3期

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