摘要
Reaction of（NH4）2 Ce（NO3）6 first with NaOtBu in a 1：6 molar ratio in THF, then with an equivalent of 2-bis（salicylidieneamino）methylphenol（H3 salmp） affords the（salmp）2 Ce2-（O）Na4（OtBu）4（THF）4 ·2C6 H6 complex. It crystallizes in monoclinic, space group C2/c with a = 16.5218（14）, b = 23.992（2）, c = 21.9454（18）, β = 97.470（1）°, V = 8625.1（12）3, Z = 4, Mr = 1811.96, Dc = 1.395 g/cm3, μ = 1.126 mm-1, F（000） = 3736, S = 1.061, R = 0.0405 and wR = 0.0932（I 〉 2σ（I））.
Reaction of（NH4）2 Ce（NO3）6 first with NaOtBu in a 1：6 molar ratio in THF, then with an equivalent of 2-bis（salicylidieneamino）methylphenol（H3 salmp） affords the（salmp）2 Ce2-（O）Na4（OtBu）4（THF）4 ·2C6 H6 complex. It crystallizes in monoclinic, space group C2/c with a = 16.5218（14）, b = 23.992（2）, c = 21.9454（18）, β = 97.470（1）°, V = 8625.1（12）3, Z = 4, Mr = 1811.96, Dc = 1.395 g/cm3, μ = 1.126 mm-1, F（000） = 3736, S = 1.061, R = 0.0405 and wR = 0.0932（I 〉 2σ（I））.
基金
supported by Jiangsu Key Laboratory for the Environment Functional Materials
the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
