期刊文献+

Cu_2V_2O_7的合成及电化学性能 被引量:2

Synthesis and Electrochemical Performance of Cu_2V_2O_7
下载PDF
导出
摘要 采用溶胶凝胶法制备了锂离子电池负极材料Cu2V2O7,分别用X射线衍射仪,电子扫描电镜对产物的结构和微观形貌进行表征。结果表明,合成产物纯度高,微粒形貌规整、表面光滑、粒径小。用其组装的电池经恒流充放电测试表明,样品初始放电比容量为682.8mAh/g,具有良好的循环性能。 Cu2 V2O7 was prepared by sol gel method as cathode materials for Li-ion battery. The structure and morphology of the sample were characterized by XRD and SEM. The results show that the powder is the spherical particle with high purity, smooth surface, and small particle size. The electrochemical prop- erties of the sample are also investigated with charge and discharge tests. Synthesized by sol-gel method, Cu2 V2 O7 cathode materials present a good cycling performance with the initial specific discharge capacity of 682.8 mAh/g.
出处 《有色金属(冶炼部分)》 CAS 北大核心 2014年第2期57-60,共4页 Nonferrous Metals(Extractive Metallurgy)
基金 湖北省自然科学基金资助项目(2012FFB04906) 武汉科技大学基金项目(2011xz012)
关键词 溶胶凝胶法 锂离子电池 Cu2V2O7 sol-gel Li ion battery Cu2 V2O7
  • 相关文献

参考文献11

  • 1张绍岩,燕红,高岩磊,常永芳,牟微.钒酸铜纳米线的制备及光吸收性能[J].人工晶体学报,2011,40(6):1517-1520. 被引量:4
  • 2YIN Wen-yin,WANG Wen-zhong,SHANG Meng. BiVO4 hollow nanospheres:anchoring synthesis,growth mechanism,and their application on photocatalysis[J].{H}European Journal of Inorganic Chemistry,2009.4379-4384.
  • 3Ponomarenko L A,Vasil'ev A N. Magnetic properties of Cu2V2O7[J].{H}PHYSICA B,2000,(2):1459-1460.
  • 4Kataev V,Pommer J,Choi K Y. Mangnetic exchange in a low-dimensional complex oxide (Cu,Zn)2V2O7[J].{H}Journal of Magnetism and Magnetic Materials,2004.933-934.
  • 5Touaiher M,Rissouli K,Benkhouja K. Crystal structures and magnetic properties of M2 V2 O7 (M =Co,Ni and Cu) compounds[J].Materials Chemistry and Physics Phys,2004,(1):41-46.
  • 6Buckley A M,Bramwell S T,Day P. The magnetic properties and structures of the transition metal pyroarsenates M2As2O7 (M =Ni,Co,Mn)[J].{H}Journal of Solid State Chemistry,1995,(1):229-235.
  • 7CAO Jun-qi,WANG Xian-you,TANG An-ping. Sol-gel synthesis and electrochemical properties of CuV2O6 cathode material[J].{H}Journal of Alloys and Compounds,2009.875-878.
  • 8WU Xing-Ming,LI Xin-Hai,XIAO Zhuo-Bing. Synthesis and characterization of LiMn2O4 powders by the combustion-assisted sol-gel technique[J].{H}Materials Chemistry and Physics,2004.182-186.
  • 9Thirunakarana R,Ravikumara R,Vanithab S. Glutamic acid-assisted sol-gel synthesis of multi-doped spinel lithium manganate as cathode materials for lithium rechargeable batteries[J].{H}Electrochimica Acta,2011.348-358.
  • 10L Yun-sung,S Yang-kook,N Kee-Suk. Synthesis of spinel LiMn2O4 cathode material prepared by an adipic acid-assisted sol-gel method for lithium secondary batteries[J].Solid Sate Ionics,1998.285-294.

二级参考文献18

  • 1HJELM Anna-Karin, TOM Eriksson, GORAN Lindberdh. Electrochemical investigation of LiMn2O4 cathodes in gel electrolyte at various temperatures[J]. Electrochemica Acta, 2002,48 : 171-179.
  • 2PARK Y J,KIM J G,KIM M K,et al. Preparation of the LiMn2O4 thin films by a sol-gel method[J]. Solid State Ionics, 2000,30 ( 3 -4) .. 203 -214.
  • 3LEE Yun-Sung,SUN Y K,NAHM K S. Synthesis of spinel LiMn2O4 cathode material prepared by an adipic acid-assisted sol-gel method for lithium secondary batteries[J]. Solid State Ionics, 1998,109(3-4) :285-294.
  • 4PRABAHARAN S R,SAPARINL N B ,MICHANEL S S,et al. Synthesis of spinel Li1.05Mn2o4 cathode material prepared by assisted sol-gel method for lithium secondary[J]. Solid State Ionics, 1998,112(1-2) :25-34.
  • 5SUN Yang-Kook,LEE Kyeong-Hee ,MOON Seong-In, et al. Effect of crystallinity on the electrochemical behaviour of spinel Li1.03Mn2O4 cathode material[J]. Solid State Ionica, 1998,112(3/4) :237-243.
  • 6HWANG B J,SANTHANAM R,LIU D G. Characterization of nanoparticles of LiMn2O4 synthesized by citric sol-gel method[J]. Power Sources, 2001,97-98 : 443-446.
  • 7Andrukaitis E,Cooper J P,Smit J H.Lithium Intercalation in the Divalent Metal Vanadates MeV2O6 (Me =Cu,Co,Ni,Mn or Zn)[J].J.Power Sources,1995,54:465-469.
  • 8Andrukaitis E.Study of Lithium Insertion into Mex V2O5+x/2,Me =copper,Iron or Chromium[J].J.Power Sources,1997,68:656-659.
  • 9Yin W Z,Wang W Z,Shang M,et al.BiVO4 Hollow Nanospheres:Anchoring Synthesis,Growth Mechanism,and Their Application in Photocatalysis[J].Eur.J.Inorg.Chem.,2009,29-30:4379-4384.
  • 10Song J M,Lin Yun Z,Yao H B,et al.Superlong α-AgVO3 Nanoribbons:High-Yield Synthesis by a Pyridine-Assisted Solution Approach,Their Stability,Electrical and Electrochemical Properties[J].ACS Nano,2009,3:653-660.

共引文献5

同被引文献12

引证文献2

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部