摘要
以5,6-二氯呋咱并[3,4-b]吡嗪为初始原料,经肟化、呋咱成环、成盐3步反应合成标题化合物;确定反应的最适宜条件:溶剂配比V(甲醇)∶V(水)=10∶1,物料比n(DFP)∶n(KOH)=1∶2.2,收率达91.6%。采用差示扫描量热(DSC)考察了目标化合物的热性能,结果显示双呋咱并[3,4-b:3',4'-e]吡嗪二钾盐具有较好的热稳定性。
Dipotassium salt of difurazano [ 3,4-b： 3′, 4′-e ] pyrazine（DFPK） was synthesized using 5,6-Dichlorofurazano [ 3,4-b ] pyrazine as starting material, via oxime, cyclization and salification. The optimum condition was followed as：the solvent was water/methanol（volume ratio is 10：1 ） ,the molar ratio of DFP and KOH was 1 ： 2.2, the yield of target com- pound was 91.6%. The thermal performance of DFPK was studied using differential scanning calorimetry （ DSC ） , result show that DFPK have preferable thermal stability.
出处
《化学试剂》
CAS
CSCD
北大核心
2014年第3期215-216,247,共3页
Chemical Reagents
基金
国防科工局基础科研计划项目(B09201100051)
关键词
双呋咱并[3
4-b
3′
4′-e]吡嗪二钾盐
合成
表征
热性能
dipotassium salt of difurazano [ 3,4-b ： 3′, 4′-e ] pyrazine
synthesis
characterization
thermal performance
