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Pitzer混合参数对HCl-NaCl-H_2O体系溶解度预测的影响 被引量:7

Effects of Pitzer Mixing Parameters on the Solubility Prediction of the Phase System HCl- NaCl- H_2O
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摘要 This paper reports the results of solubility calculation of the phase system HCl- NaCl- H2O at 25℃ whenθ HNa (interactions of two species with the same charge) andΨ HNaCl (interactions of three species) were changed by+ 10% and- 10% . The results indicated that the effects of the two kinds of interactions on the calculated solubility of the system were regular. The calculated solubilities of the system did not vary while the two interactions were increased and decreased simultaneously. The solubility data of the system changed greatly as one interaction was increased and the other decreased. This study is significant for the chemical technology of salting out salts from the water- salt system. This paper reports the results of solubility calculation of the phase system HCl- NaCl- H2O at 25℃ whenθ HNa (interactions of two species with the same charge) andΨ HNaCl (interactions of three species) were changed by+ 10% and- 10% . The results indicated that the effects of the two kinds of interactions on the calculated solubility of the system were regular. The calculated solubilities of the system did not vary while the two interactions were increased and decreased simultaneously. The solubility data of the system changed greatly as one interaction was increased and the other decreased. This study is significant for the chemical technology of salting out salts from the water- salt system.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 2001年第1期91-94,共4页 Acta Physico-Chimica Sinica
基金 中国科学院重点课题! (No.970393) 西北大学博士基金
关键词 PITZER混合参数 活度系数 溶解度预测 氯化钠 氯化氢 电解质溶液 Pitzer mixing parameters, Activity coefficient, Solubility prediction
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  • 1赵凯元,雷鸿毅.用玻璃电极测定直到15m的浓盐酸体系的活度系数[J].物理化学学报,1986(1):30-36. 被引量:3
  • 2胡克源,柳大纲科学纪著选集,1997年
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  • 6胡克源,柴文琦.O中0℃时相平衡的研究[J]化学学报,1965(03).

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