摘要
对由非光学活性底物不对称构建磷手性中心的方法进行综述,根据底物的结构以及机理的不同分为两类介绍,分别是前对映异构体的去对称化以及不同取代底物的化学拆分.
Methods for enantioselective synthesis of P-stereogenic compounds from non-optically active substmtes are reviewed. Two stategies can be classified according to the substrates and mechanisms of their reactions, which include enanti-oselective desymmetrisations and chemical resolutions.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2014年第2期292-303,共12页
Chinese Journal of Organic Chemistry
关键词
手性磷化物
不对称合成
手性拆分
P-stereogenic compound
asymmetric synthesis
chiral resolution
