具有正温度系数特性的导电低密度聚乙烯基复合材料的摩擦磨损性能

Friction and Wear Behaviour of Low-density Polyethylene Matrix Composites with Positive Temperature Coefficient Characteristics

采用共混法制备了以低密度聚乙烯为基体的含碳黑的导电复合材料 ,考察了导电复合材料的摩擦磨损性能及正温度系数特性 ,同时探讨了导电复合材料的摩擦熔融现象对其摩擦磨损性能的影响 .结果表明 :当低密度聚乙烯基导电复合材料与 GCr15钢配副时 ,在较高 pv值下 ,摩擦系数呈现周期性降低现象 ;温度对复合材料的导电性能具有重要影响 ,而聚四氟乙烯及聚苯酯等辅助导电剂对其 PTC特性无影响 .

Low-density polyethylene (LDPE) matrix conductive composites containing carbon black (CB) were prepared by mold compression. The effect of friction-induced melting on the friction and wear behaviour of the composites was explored. As the results, the electric conductivity of the composite is highly dependent on temperature; the auxiliary electric conductive agents such as polytetrafluoroethylene (PTFE) and ekonol have no effect on the PTC characteristic of the composite. A periodical decrease of the friction coefficient has been observed under a relatively high pv value in sliding of the composite pin against AISI1045 steel disc. This is related to the friction-induced melting of the LDPE matrix during the sliding process.