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有氧条件下聚(氯乙烯)负载Pd(Ⅱ)配合物高效催化Heck和无铜Sonogashira反应(英文) 被引量:2

Poly(vinyl chloride)-supported Pd(Ⅱ) complex as an efficient catalyst for Heck and Cu-free Sonogashira reactions under aerobic conditions
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摘要 A novel poly(vinyl chloride)-supported Pd complex was found to be a highly active catalyst for the Heck and Sonogashira reactions of aryl halides under aerobic conditions.The complex is thermally stable,and can be easily recovered and reused.The catalyst was recycled for the Heck and Sonogashira reactions for five runs without appreciable loss of its catalytic activity,and with negligible metal leaching. A novel poly(vinyl chloride)-supported Pd complex was found to be a highly active catalyst for the Heck and Sonogashira reactions of aryl halides under aerobic conditions. The complex is thermally stable, and can be easily recovered and reused. The catalyst was recycled for the Heck and So-nogashira reactions for five runs without appreciable loss of its catalytic activity, and with negligible metal leaching.
机构地区 School of Chemistry
出处 《催化学报》 SCIE EI CAS CSCD 北大核心 2014年第3期324-328,共5页
基金 the financial support of the Research Council of Shahrood University of Technology
关键词 HECK 催化剂 氯乙烯 反应 好氧条件 PD 载体 配合物 Heck reaction Sonogashira reaction Awl halide Poly(vinyl chloride)-anchored palladium(II) dithizone complex
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