摘要
A new 2D coordination polymer, [Cd（tpim）（1,5-nds）]n （1）, was constructed from 1,5-naphthalenedi- sulfonate （1,5-nds）. 2.4,5-tri（4-pyridyl）-imidazole （tpim） and Cd（CH3COO）2.2H2O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of I in the solid state were also investigated.
A new 2D coordination polymer, [Cd（tpim）（1,5-nds）]n （1）, was constructed from 1,5-naphthalenedi- sulfonate （1,5-nds）. 2.4,5-tri（4-pyridyl）-imidazole （tpim） and Cd（CH3COO）2.2H2O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of I in the solid state were also investigated.
基金
financial support from the National Natural Science Foundation of China(No.21272109)
the Natural Science Foundation of Henan Province (No.112300410138)
the Foundation of the Education Department of Henan Province(No.2011B150021)
Luoyang Science and Technology Fund
