摘要
四芳基取代环戊二烯酮与二氟取代二苯乙炔通过Diels-Alder环加成反应制得六芳基取代苯(6);6在路易斯酸催化下通过Scholl环氧化脱氢反应合成了一个新型的氟取代六苯并蔻衍生物———1,3,5,8,10,12,14,17-八氟代六苯并蔻(7),收率70%,其结构经1H NMR,13C NMR和MS表征。TG研究结果表明,7失重5%的温度为452℃。
Hexaarylbenzene derivative （6） was prepared by Diels-Alder cycloaddition reaction of tetraaryl cyclopentadienone with 4,4＇-difluorodiphenylacetylenes.A novel fluorine substituted hexaperi-hexabenzocoronene derivative——1,3,5,8,10,12,14,17-octafluoro-hexa-peri-hexabenzocoronene （7） in yield of 70% was synthesized by Scholl cyclodehydrogenation of 6 using FeCl3 asthe catalyst.The structures were characterized by 1H NMR,13C NMR and MS.Thermal stability of 7 was investigated by TG and the results indicated that 5% weight loss temperature was 452 ℃.
出处
《合成化学》
CAS
CSCD
北大核心
2014年第2期204-206,221,共4页
Chinese Journal of Synthetic Chemistry
基金
国家自然科学基金资助项目(21172035)
关键词
六苯并蔻
Scholl环氧化
合成
热稳定性
hexabenzocoronene
Scholl cyclodehydrogenation
synthesis
thermal stability
