期刊文献+

快速合成单分散聚苯乙烯纳米微球 被引量:2

Rapid Synthesis of Monodisperse Polystyrene Nanospheres
下载PDF
导出
摘要 利用沸腾无皂乳液聚合法制备了粒径均一的聚苯乙烯(PS)聚合物纳米微球,考察了单体浓度、反应时间对所得微球的影响以及聚合过程中微球形貌随反应时间的变化。实验结果表明:通过优化反应条件,可实现单分散PS微球的快速合成。 Monodispersed polystyrene (PS) nanospheres are synthesized by boiling emulsifier-free emulsion polymerization. The effects of the reaction parameters such as the monomer concentration and the reaction time were investigated, and the morphologies of the nanospheres during growth were also characterized. The results showed that the PS nanospheres with uniform structures could be synthesized rapidly by modifying the reaction conditions.
出处 《上海第二工业大学学报》 2014年第1期9-12,共4页 Journal of Shanghai Polytechnic University
基金 上海高校特聘教授(东方学者)岗位支持计划 上海市科委基础研究重点项目(No.13NM1401300) 上海高校青年教师培养资助计划(No.ZZegd12001) 上海第二工业大学校科研启动基金(No.A30XK121101 No.EGD13XQD14) 上海市人才发展基金(No.201346) 上海第二工业大学校级重点学科(第四期)建设项目(No.XXKPY1302)资助
关键词 无皂乳液聚合 单分散 聚苯乙烯 纳米微球 emulsifier-flee emulsion polymerization monodisperse polystyrene nanospheres
  • 相关文献

参考文献15

  • 1FITCH R M. The science of polymer colloids: the state of the art [J]. Macromolecular Symposia, 1995, 92(1): 1-11.
  • 2DICKINSON E, PARKER R. Polydispersity and the col- loidal order-disorder transition [J]. Chemical Physics Let- ters, 1981, 79(3): 578-582.
  • 3ZOU H, WU S S, SHEN J. Polymer/silica nanocomposites: preparation, characterization, properties, and applications [J]. Chemical Reviews, 2008, 108(9): 3893-3957.
  • 4REESE C E, GUERRERO C D, WEISSMAN J M, et al. Synthesis of highly charged, monodisperse polystyrene colloidal particles for the fabrication of photonic crystals [J]. Journal of Colloid and Interface Science, 2000, 232(1): 76-80.
  • 5REESE C E, ASHER S A. Emulsifier-free emulsion poly- merization produces highly charged, monodisperse parti- cles for near infrared photonic crystals [J]. Journal of Col- loid and Interface Science, 2002, 248(1), 41-46.
  • 6GU Z Z, CHEN H H, ZHANG S, et al. Rapid synthesis of monodisperse polymer spheres for self-assembled pho- tonic crystals [J]. Colloids and Surfaces A: Physicochemi- cal and Engineering Aspects, 2007, 302(1 ): 312- 319.
  • 7LEON-BERMISIDEZ A, SALAZAR R. Synthesis and characterization of the polystyrene-asphaltene graft copolymer by FT-IR spectroscopy [J]. C. T. & F Ciencia, Tecnologfa, Futuro, 2008, 3(4): 157-167.
  • 8RADHI M M, TAN W T, AB RAHMAN M Z B, et al. Synthesis and characterization of grafted acrylonitrile on polystyrene modified with activated carbon using gamma- irradiation [J]. Scientific Research and Essays, 2012, 7(7):790-795.
  • 9BUTLER I B, SCHOONEN M A A, RICKARD D T. Re- moval of dissolved oxygen from water: A comparison of four common techniques [J]. Talanta, 1994, 41(2): 211- 215.
  • 10YAMAMOTO Y, AOKI K, ICHIKAWA N, et al. Noncon- densable gas accumulation phenomena in nuclear power plant piping [J]. Journal of Nuclear Science and Technol- ogy, 2011, 48(7): 1004-1016.

同被引文献5

引证文献2

二级引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部