摘要
The effects of BaCu(B2Os) (BCB) addition on the microstructure, phase formation, and microwave dielectric proper- ties of BasNb4015-BaWO4 ceramic are investigated. As a sintering aid, BaCu(B2Os) ceramic could effectively lower the sintering temperature of BasNb4015-BaWO4 ceramic from 1100 ℃ to 950 ℃ due to the liquid-phase effect. Meanwhile, BaCu(B2Os) addition effectively improves the densification of BasNb4015-BaWO4 ceramic and significantly influences the microwave dielectric properties. X-ray diffraction analysis reveals that BasNb4015 and BaWO4 coexist with no crystal phase of BaCu(B2Os) in the sintered ceramics. The BasNb4015-BaWO4 ceramics with 1.0 wt% BaCu(B2Os) sintered at 950 ℃ for 2 h presents good microwave dielectric properties of er = 19.0, high Q× f of 33802 GHz and low vf of 2.5 ppm/℃.
The effects of BaCu(B2Os) (BCB) addition on the microstructure, phase formation, and microwave dielectric proper- ties of BasNb4015-BaWO4 ceramic are investigated. As a sintering aid, BaCu(B2Os) ceramic could effectively lower the sintering temperature of BasNb4015-BaWO4 ceramic from 1100 ℃ to 950 ℃ due to the liquid-phase effect. Meanwhile, BaCu(B2Os) addition effectively improves the densification of BasNb4015-BaWO4 ceramic and significantly influences the microwave dielectric properties. X-ray diffraction analysis reveals that BasNb4015 and BaWO4 coexist with no crystal phase of BaCu(B2Os) in the sintered ceramics. The BasNb4015-BaWO4 ceramics with 1.0 wt% BaCu(B2Os) sintered at 950 ℃ for 2 h presents good microwave dielectric properties of er = 19.0, high Q× f of 33802 GHz and low vf of 2.5 ppm/℃.
基金
Project supported by the National Natural Science Foundation of China(Grant Nos.51372031,61171047,51132003,and 61271038)
the Program for New Century Excellent Talents in University,China(Grant No.NCET-12-0090)
Science Fund from the Science and Technology Department of Sichuan Province,China(Grant No.2013GZX0144)