3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构(英文)

Crystal Structures of Cobalt(Ⅱ) and Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole

以3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑(Athpp)为配体合成了2个金属配合物即CoCl4(Athpp)2·2H2O(1)和CuCl4(Athpp)2(2)。用红外、元素分析和X-射线单晶衍射等手段表征了晶体结构。配合物1结晶在P1空间群而配合物2结晶在P21/n空间群。金属中心均采取扭曲八面体构型。此外。

Two compounds CoCl4（Athpp）2 ·2H2O （1） and CuCl4（Athpp）2 （2） were respectively obtained by the reactions of 3-amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole （Athpp） with cobalt（n） chlorine and copper（n） chlorine. The compounds have been characterized by FT-IR, elemental analyses and crystal structures. The compound 1 crystallizes in P1 space group and the compound 2 crystallizes in P2 1/n space group. The central metals are adopt distorted octahedral geometry. In addition, the fluorescent spectroscopy of the compounds were studied in solid state at room temperature. CCDC： 961605, 1; 961606, 2.