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Research on Assembly and catalysis of Transition Metal Organic Complexes

Research on Assembly and catalysis of Transition Metal Organic Complexes
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摘要 We designed and synthesized ligand L1 with C3 synametry in the paper, through self-assembly with silver nitrate obtained complexes 1 of silver double helix with three nuclear, that were used to characterize its structure by NMR and mass spectrometry, the complex silver as the catalytic sites, and the ligand L of hydrogen on the nitrogen fell microphone has certain basic, that can be used as an auxiliary Methylene dehydrogenation of Isopropyl methyl cyanoacetate, thereby accelerating the reaction. Further, the introduction of a chiral ligand to give complexes 2, to achieve an asymmetric aldol reaction of methyl isocyanoacetate.
出处 《International Journal of Technology Management》 2014年第3期12-14,共3页 国际技术管理
关键词 Metal-organic compound Trinity helix Dinuclear helix 过渡金属有机配合物 催化 加速反应 手性配体 硝酸银 乙酸甲酯 复合物 螺旋带
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