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笼状氮杂三咪唑鎓环番的“一锅法”合成与结构表征

One-pot Synthesis and Structural Characterization of Cage Aza-tri-imidazolium Cyclophanes
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摘要 以2,2',2″-三氯乙基胺盐酸盐、咪唑或苯并咪唑为起始物,经中间产体-氮杂三咪唑1、氮杂三苯并咪唑2,继而在高稀淡条件下采用"一锅法"合成了笼状氮杂三咪唑鎓环番3、4、笼状氮杂三苯并咪唑鎓环番5;经IR和1H NMR、13C NMR,MS谱表征了环番3、4、5的结构. Cage aza-tri-imidazolium cyclophanes 3,4,5 have been synthesized via intermediate Aza-tri-imidazolium 1 or Aza-tri-benzimidazolium 2 reacting with tribromide compounds by one-pot method under high dilution condition,with 2,2＇,2″-trichloroethylamine hydrochloride,imidazole and benzimidazole as the starting materials.The structures of cyclophanes 3,4,5 were characterized by IR,1H NMR,13C NMR and MS.
作者 彭琼 蒋宗林 陈琳 马利霞 李宇飞
机构地区 西华师范大学化学化工学院
出处 《西华师范大学学报（自然科学版）》 2014年第1期41-44,共4页 Journal of China West Normal University(Natural Sciences)
基金 四川省教育厅自然科学基金重点项目(13ZA0009)
关键词 笼状环番 咪唑鎓 合成 cage-cyclophanes imidazolium synthesis
分类号 O626.23 [理学—有机化学]
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参考文献21

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西华师范大学学报（自然科学版）
2014年 第1期

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